• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Small power absorption refrigeration machine. The present invention relates to a refrigeration machine of low power absorption that allows to work with air as a refrigerant and has an evaporation unit that is separated from the rest of the absorption refrigeration machine and that works with solutions libr/h2 o, h2 o/nh3, lino3/nh3 or similar setting an air-air machine, where the cold is produced directly in the enclosure that you want to air-condition without the need for impulsion pumps and fan coils. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2555704A2
    申请号:ES201430831
    申请日:2014-05-30
    公开日:2016-01-07
    发明作者:Marcelo IZQUIERDO MILLÁN；Emilio MARTÍN LÁZARO
    申请人:Consejo Superior de Investigaciones Cientificas CSIC；
    IPC主号:
    专利说明:

    Small power refrigeration absorption machine
    D E S C R I P C I ON
    5 OBJECT OF THE INVENTION
    The present invention relates to a small power refrigeration absorption machine that allows working with air as a refrigerant and has an evaporation unit that is separated from the rest of the absorption refrigeration machine.
    10
    The object of the small power absorption refrigeration machine of the present invention is to work with LiBr / H2O, H2O / NH3, LiNO3 / NH3 or similar solutions by configuring an air-to-air machine, where the cold is produced directly in the enclosure that is You want to air-conditioning without the need for impulsion pumps and fancoils.
    fifteen
    BACKGROUND OF THE INVENTION
    The refrigeration absorption cycle is an alternative, among others, to the mechanical steam compression cycle. The refrigerating machines that operate according to this cycle and which are currently marketed are the lithium-water bromide absorption refrigerating machine and the water-ammonia refrigerating machine.
    The first uses the aqueous solution of lithium bromide as a working fluid, with lithium bromide being the absorbent and water the refrigerant; In the second case, the working fluid is a solution of ammonia in water, working water as an absorbent and ammonia as a refrigerant.
    In both cases, the source of energy is heat, which can come from the combustion of a fossil or renewable fuel, from residual motor heat or from 30 thermal processes or from the thermal conversion of solar energy or biomass among others. , this being the main difference with the mechanical steam compression refrigeration machine.
    On the other hand, both solutions, both the aqueous lithium bromide and the fluid of
    work, such as water-ammonia with water working as an absorbent and ammonia as a refrigerant, have different characteristics that affect the operation of the machines. The lithium-water bromide machine cannot work at a temperature below 0 ° C and the solution under certain conditions can crystallize by paralyzing the production of cold, while the water-ammonia machine can produce cold at a temperature below zero and not it generates crystallization problems, but instead it needs a rectification column to separate the water from the ammonia before entering the condenser.
    10 Both types of machine can be built to be condensed by water or air.
    In a refrigerated absorption machine condensed by water, a system 15 consisting of a cooling tower equipped with a pump and a fan is used to carry out the condensation of the refrigerant and the cooling of the absorber. The
    The pump carries the condensation water between the tower and the condenser-absorber and the fan drives the air through the tower, transporting evaporated water to the atmosphere. The cooling tower has the disadvantage of generating Legionella contamination and consuming water, which is a scarce commodity in dry climates and arid areas.
    As for the refrigerated absorption machines condensed by air, those of simple effect work with the solution water-ammonia and lithium bromide-water but both are of indirect system, since they produce the cold in the evaporator that is separated from the enclosure to be heated, so that in order to transport the cold to the feeding points in the building it is necessary to pump the cold water or a solution, with the consequent need for the use of a pump and a fan coil. Half-effect and multi-effect ones also use an indirect system to transport the cold.
    The small power absorption machine of the present invention solves all the above drawbacks.
    DESCRIPTION OF THE INVENTION
    The present invention relates to a small power absorption refrigeration machine, with small power being understood as machines of less than 15 kW of power, working with LiBr / H2O, H2O / NH3, LiNO3 / NH3 or similar solutions for use in air conditioning or refrigeration installations comprising an outdoor unit and an indoor unit.
    The outdoor unit includes:
    - an absorber capable of keeping the pressure and evaporation temperature 10 low when the outside temperature is high, cooled directly by outside air or by water, which carries out separate processes of heat and mass transfer, a condenser directly cooled by air outside, at least one coolant generator, and one heat recuperator.
    The coolant generator comprises at least one heating chamber in which a heat exchanger can be found, preferably constructed of refractory stainless steel or other high temperature resistant material, when the heat source is of direct flame, so that facilitate heat transfer to the solution of lithium bromide-water; heat exchanger that can use the heat 20 produced by a field of solar collectors, by a biomass boiler, by a biodiesel boiler, by a bioethanol boiler, by a conventional fossil fuel boiler, or the residual heat of exhaust gases from engines, batteries or fuel cells, or any thermal process that generates residual heat at sufficient temperature.
    25
    The generator can also alternatively or complementaryly incorporate a modulating burner of small, medium or high power controlled by a PDI regulator that allows controlling the temperature at will, which generates heat in the heating chamber as a result of the combustion of a fuel. fossil, preferably LPG, GN, Diesel, Biodiesel, Biogas or others.
    Additionally, in the case of LiBr / H2O solutions, the generator has a water vapor separator in the heating chamber. In this case, the working solution is introduced diluted into the heating chamber of the
    generator, absorbs heat, boiling at a temperature between 85 ° C and 115 ° C or higher, depending on the T of the outside air, producing superheated refrigerant vapor, which is separated in the separator and hot and concentrated solution. Water vapor leaves the generator and is directed to the condenser, 5 where it is transformed into liquid, to be directed to continuation through an expansion valve to the evaporator where it is transformed back into water vapor. In the case of H2O / NH3 and LiNO3 / NH3 solutions, the process is similar since the total separation of the refrigerant occurs in a rectifying column or tower.
    10
    The heat recuperator is preferably a copper-welded plate exchanger, in the case of LiBr / H2O solutions, and transfers heat from the hot and concentrated solution that exits the generator to the diluted and cold solution that comes from the absorber , preheating it, before being fed to the generator.
    fifteen
    The hot and concentrated solution from the generator crosses the recuperator and reduces its pressure in a reducing valve located between the recuperator and the absorber, to enter the absorber at a lower pressure.
    The absorber comprises a storage tank, a battery of sprayers located inside the storage tank through which the hot and concentrated solution passes for spraying inside the tank where on contact with the water vapor from the evaporator is dilutes, a heat exchanger, outside the storage tank and preferably finned, which
    25 cools the diluted solution, a recirculation pump that aspirates the diluted solution
    from the storage tank and drives it to the heat exchanger from which the cooled diluted solution comes out returning to the battery of sprayers in a continuous process of recirculation, enhancing the increase in mass and heat transfer. This recirculation pump also supplies diluted solution to the generator
    30 through the heat recuperator where it is preheated before entering the generator, where the solution is concentrated again.
    The absorber transmits the heat of absorption of the solution directly to the atmospheric air, through the heat exchanger.
    The indoor unit comprises:
    - at least one expansion valve that connects the condenser with a direct expansion evaporator 5 through a conduit through which the liquid refrigerant K passes at high pressure. In the expansion valve, the pressure and temperature are reduced to the evaporator operating values. The liquid and vapor phase refrigerant passes to a refrigerant receiver that supplies it to the evaporator which in turn comprises
    - a distributor of liquid refrigerant,
    10 - a water-air heat exchanger,
    - a water vapor collector, ammonia, etc. integrated in the water-air heat exchanger,
    - a fan that sucks the air in the room to be heated and drives it cold by mixing it with the hot air in the room.
    fifteen
    The outdoor unit is separated from the indoor unit and both are connected by two conduits, the above-described conduit through which the high-pressure liquid refrigerant K passes and a conduit that transports the vapor refrigerant from the evaporator of the indoor unit to the unit outside once said refrigerant has been evaporated.
    Therefore, the object of the small power absorption refrigeration machine of the present invention is to work with LiBr / H2O, H2O / NH3, LiNO3 / NH3 or similar solutions by configuring an air-to-air machine, where the cold is produced directly in the enclosure that is to be heated without the need for impulsion pumps and fancoils of indirect systems that increase the electricity consumption of auxiliary components and raise the cost of the machine.
    There are variants for a double-acting, single-acting and double-acting refrigeration absorption machine built in a unit, triple-acting and single and triple-acting built in a unit, as will be described in the preferred embodiment of the invention.
    When the evaporator arranged in the indoor unit and the absorber are separated
    provided in the outdoor unit a distance of at least 1 m between axles, preferably between 1 and 2 m or more than 2 m, the machine is split type. This distance could be increased depending on the application and the solution. In this way, the liquid refrigerant produced in the condenser is transported a certain distance to the evaporator and once evaporated returns to the aspiration of the absorber that coincides with the aspiration of the thermal compressor, which is formed by the absorber, the recirculation pump -generator, coolant generator, heat recuperator and pressure reducing valve, without any other mechanical intermediate system between the condenser and the compressor aspiration, to
    10 Recover it and restart the cycle. At the outlet of the thermal compressor, that is, at the outlet of the generator, the refrigerant is in the vapor phase, reheated, which is fed to the condenser, to transform it into a liquid and supply it to the expansion valve.
    15 DESCRIPTION OF THE DRAWINGS
    To complement the description that is being made and in order to help a better understanding of the characteristics of the invention, according to a preferred example of practical realization thereof, it is accompanied as an integral part of
    20 said description, a set of drawings where, with an illustrative and non-limiting nature, the following has been represented:
    Figure 1.- Shows a scheme of the small power absorption refrigeration machine of the present invention when it is of the simple effect type.
    25
    Figure 2.- Shows a scheme of the direct expansion evaporator of the small power absorption refrigeration machine of the present invention for configuring a double effect small power absorption machine.
    Figure 3.- Shows a scheme of the direct expansion evaporator of the small power absorption refrigeration machine of the present invention for configuring a single and double effect small power absorption machine constructed in a unit.
    Figure 4.- Shows a scheme of the direct expansion evaporator of the small power absorption refrigeration machine of the present invention to configure a triple effect small power absorption machine.
    5 Figure 5.- Shows a scheme of the direct expansion evaporator of the small power absorption refrigeration machine of the present invention to configure a small and triple effect small power absorption machine built in a unit.
    10 PREFERRED EMBODIMENT OF THE INVENTION
    In accordance with the scheme shown in Figure 1, the small power absorbing refrigerating machine of the present invention, single acting with a solution of lithium bromide for this preferred embodiment comprises an outdoor unit (200) and an indoor unit (100)
    The outdoor unit (200) comprises:
    - a refrigerant generator (1) that has a heating chamber (2) adapted to heat a solution of lithium-water bromide that includes a
    20 water vapor separator (not shown),
    - an absorber (3) comprising: a storage tank (4), a spray tank (5) located inside the storage tank (4) through which the hot and concentrated solution is passed which is projected afterwards in the inside the storage tank (4) for dilution, a heat exchanger (6) in the
    25 outside the storage tank (4) that cools the diluted solution, a recirculation-generator pump (7) that aspirates the diluted solution from the storage tank (4) and drives it to the generator (1), for its concentration and to the heat exchanger (6) from which the diluted diluted solution comes out returning to the spray booth (5) in a continuous recirculation process, and 30 - a heat recuperator (9) located between the generator (1) and the absorber (3) in the
    that the heat of the hot and concentrated solution that leaves the generator (1) is transferred to the diluted solution and that comes from the absorber (3), preheating it, before being fed to the generator (1),
    - a pressure reducing valve (10) located between the heat recuperator (9) and the
    absorber (3),
    - a condenser (11) connected to the generator (1) that condenses the water vapor produced in the generator (1),
    connected to the evaporator (12) adapted to introduce water vapor into the absorber (3).
    In the case of using a water-ammonia solution, the steam separator is replaced by a fractionation column.
    In a first embodiment example shown in Figure 1, the indoor unit (100) comprises:
    - an expansion valve (13) that connects the condenser (11) with an evaporator (12) through a conduit (101) through which the high-pressure liquid refrigerant passes through a refrigerant receiver (102) in phase liquid and in vapor phase at low
    15 pressure, where in the expansion valve (13) the pressure and temperature are reduced to the evaporator operation values (12): which as an example, not exhaustive, can be the following: a pressure between 10 and 15 mbar and a temperature between 10 ° C and 15 ° C for a solution of LiBr / H2O, and a pressure between 1.5 and 5 bar and a temperature between -25 ° C and 15 ° C for H2O / NH3 and 20 solutions LiNO3 / NH3. As a consequence there is a partial evaporation of the refrigerant.
    The pressure values in the condenser are between approximately 10 and 20 bar, for the H2O / NH3 and LiNO3 / NH3 solutions, and between approximately 0.05 and 0.15 bar, for the LiBr / H2O solution.
    The evaporator (12) is a direct expansion evaporator comprising:
    - a distributor of liquid refrigerant (103).
    - a water-air heat exchanger (104) comprising a set of finned tubes.
    - a water vapor collector, ammonia, etc. (105) integrated in the evaporator (12),
    30
    thus configuring a single-acting direct expansion absorption machine applicable to any solution that is used as a working fluid, among which are lithium bromide-water (LiBr / H2O), water-ammonia (H2O / NH3) ; lithium ammonia nitrate (LiNO3 / H2O), or any other that needs a
    expansion valve (13).
    The refrigerant in the Kquida phase and in the low pressure steam phase is separated in the refrigerant receiver (102), where the steam is directed to the steam manifold (105) while the Kquido is transported to the Kquido refrigerant distributor (103 ) that feeds it to the evaporator (12).
    In the evaporator (12), the H2O or NH3 that act as a refrigerant depending on the solution and that are fed by the distributor (103), circulates inside the 10 tubes, where the outside fluid is the air of the room or enclosure to be cooled (18) circulating outside the tubes, cooling as a result of the low temperature produced by evaporation of the refrigerant at low pressure inside the tubes. The tubes are finned to increase the heat transfer area. The steam produced inside the pipes passes to the steam collector (105).
    fifteen
    To cool the air in the room or the room to be cooled (18), a fan (107) is used that draws hot air from the room and drives it through the outer surface of the tubes and the fins of the heat exchanger. The air is cooled and mixed with the hot air of the room or room to be cooled (18) by lowering its temperature and maintaining the interior comfort temperature.
    In a second embodiment shown in Figure 2, where the solution is lithium bromide-water (LiBr / H2O) or a solution with similar physical properties (pressure and temperature), the indoor unit (100) comprises the elements described 25 for the first embodiment, but where the evaporator (12) works with refrigerant from two expansion valves (23, 24), a first expansion valve (23) that feeds refrigerant from a low pressure generator (no shown) and a second expansion valve (24) that feeds refrigerant from a high pressure generator (not shown), thereby configuring a double-acting direct expansion absorption machine.
    In a third embodiment shown in Figure 3, where the solution is lithium bromide-water (LiBr / H2O) or a solution with similar physical properties (pressure and temperature), the indoor unit (100) comprises the elements described
    for the first example of realization, but where the evaporator (12) works with refrigerant from three expansion valves (33, 34, 35), a first expansion valve (33) that feeds refrigerant from a single-acting generator ( not shown), a second expansion valve (34) that supplies refrigerant 5 from a low pressure double acting generator (not shown) and a third expansion valve (35) that supplies refrigerant from a double acting generator high pressure (not shown), thus configuring a single and double acting direct expansion absorption machine built in a unit.
    10
    In a fourth embodiment shown in Figure 4, where the solution is lithium bromide-water (LiBr / H2O) or a solution with similar physical properties (pressure and temperature), the indoor unit (100) comprises the elements described for the first embodiment, but where the evaporator (12) works with 15 refrigerant from three expansion valves (43, 44, 45), a first expansion valve (43) that feeds refrigerant from a low pressure generator (not shown), a second expansion valve (44) that feeds refrigerant from a medium pressure generator (not shown) and a third expansion valve (45) that feeds refrigerant from a high pressure generator (not shown) ), thus configuring a triple-acting direct expansion absorption machine.
    In a fifth embodiment shown in Figure 5, where the solution is lithium bromide-water (LiBr / H2O) or a solution with similar physical properties (pressure and temperature), the indoor unit (100) comprises the elements described for the first embodiment, but where the evaporator (12) works with refrigerant from four expansion valves (53, 54, 55, 56), a first expansion valve (53) that feeds refrigerant from a generator single acting (not shown), a second expansion valve (54) that feeds 30 refrigerant from a triple effect low pressure generator (not shown), a third expansion valve (55) that feeds refrigerant from a generator triple medium pressure effect (not shown) and a fourth expansion valve (56) that feeds refrigerant from a triple effect high pressure generator (not shown), thus configuring a machine
    Direct and single effect direct expansion absorption built in a unit.
    The absorption machine further comprises a vapor refrigerant duct (106) that joins the indoor unit (100) with the outdoor unit (200) to introduce water vapor into the absorber (3).
    The heat exchanger (6) of the absorption machine is an air-dissolution exchanger, as shown in Figure 1 with a fan (16) associated with said exchanger, although it is also contemplated that maintaining the 10 particularities described in the paragraph above the heat exchanger (6) may be of the water-dissolution type.
    The fan (16) of the air-dissolution heat exchanger (6) can be the same as the fan (16) that cools the condenser (11), as shown in Figure 1.
    The generator (1) can incorporate in the heating chamber (2) a heat exchanger (not shown) and / or associated with the heating chamber may have a fossil fuel burner (not shown).
    twenty
    权利要求:
    Claims (8)
    [1]
    5
    10
    fifteen
    twenty
    25
    30
    R E I V I N D I C A C I O N E S
    1. Small power absorption refrigeration machine for use in air conditioning or refrigeration installations comprising a working solution characterized in that it comprises an outdoor unit (200) and an indoor unit (100), where the outdoor unit (200) comprises :
    - an absorber (3) capable of keeping the pressure and evaporation temperature low when the outside temperature is high, cooled directly by outside air or by water, which carries out separate processes of heat and mass transfer,
    - a condenser (11) cooled directly by outside air,
    - at least one refrigerant generator (1), and
    - a heat recuperator (9), and where the indoor unit comprises:
    - at least one expansion valve (13, 23, 24, 33, 34, 35, 43, 44, 45, 53, 54, 55, 56) that connects the condenser to a direct expansion evaporator (12) through a conduit through which the high-pressure liquid refrigerant passes through a liquid and vapor phase refrigerant receiver, where in the expansion valve (13, 23, 24, 33, 34, 35, 43, 44, 45 , 53, 54, 55, 56) the pressure and temperature are reduced to the operating values of the evaporator (12) which in turn comprises
    - a distributor (103) of liquid refrigerant,
    - a water-air heat exchanger (104),
    - a water vapor or ammonia manifold (105) integrated in the evaporator
    (12),
    - a fan (107) that sucks the air from the room to be heated and drives it cold by mixing it with the hot air of the room,
    where the outdoor unit (200) is separated from the indoor unit (100) and both are connected by two conduits, a conduit (110) through which the high-pressure liquid K refrigerant passes from the condenser (11) to the evaporator (12 ) and a conduit (106) that transports the steam refrigerant from the evaporator of the indoor unit (100) to the outdoor unit (200) once said refrigerant has passed through the evaporator (12).
    [2]
    2. Small power absorption refrigeration machine according to revindication 1 characterized in that the separation between the evaporator (12) arranged in the indoor unit (100) and the absorber (3) arranged in the outdoor unit (200) is at least 1 m between axles
    5
    [3]
    3. Small power absorption refrigeration machine according to claim 2 characterized in that the separation between the evaporator (12) arranged in the indoor unit (100) and the absorber (3) arranged in the outdoor unit (200) is 1 to 2 m.
    10 4. Small power refrigeration absorption machine characterized according to
    claim 3 characterized in that the separation between the evaporator (12) disposed in the indoor unit (100) and the absorber (3) disposed in the outdoor unit (200) is greater than 2 m.
    15 5. Small power refrigeration absorption machine according to any of the
    previous claims characterized in that the indoor unit (100) comprises two expansion valves (23, 24), a first expansion valve (23) that feeds refrigerant from a low pressure generator and a second expansion valve (24) that feeds refrigerant from a high pressure generator,
    20 thus configuring a double-acting direct expansion absorption machine.
    [6]
    6. Small power refrigeration absorption machine according to any one of claims 1 to 4 characterized in that the indoor unit (100) comprises three
    25 expansion valves (33, 34, 35), a first expansion valve (33) that feeds refrigerant from a single-acting generator, a second expansion valve (34) that feeds refrigerant from a double-acting generator low pressure and a third expansion valve (35) that feeds refrigerant from a high pressure double acting generator, configuring
    30 in this way a direct and single-acting direct expansion absorption machine constructed in a unit.
    [7]
    7. Small power refrigeration absorption machine according to any one of claims 1 to 4 characterized in that the indoor unit (100) comprises three
    expansion valves (43, 44, 45), a first expansion valve (43) that feeds refrigerant from a low pressure generator, a second expansion valve (44) that feeds refrigerant from a medium pressure generator and a third expansion valve (45) that feeds refrigerant 5 from a high pressure generator, thereby configuring a triple effect direct expansion absorption machine.
    [8]
    8. Small power absorption refrigeration machine according to any one of claims 1 to 4 characterized in that the indoor unit (100) comprises four
    10 expansion valves (53, 54, 55, 56), a first expansion valve (53) that feeds refrigerant from a single-acting generator, a second expansion valve (54) that feeds refrigerant from a triple generator low pressure effect, a third expansion valve (55) that feeds refrigerant from a triple pressure medium effect generator and a fourth 15 expansion valve (56) that feeds refrigerant from a high pressure triple effect generator, thus configuring a single and triple effect direct expansion absorption machine built in a unit.
    [9]
    9. Small power absorption refrigeration machine according to any of the previous 20 claims characterized in that the working solution is LiBr / H2O.
    [10]
    10. Small power absorption refrigeration machine according to any one of claims 1 to 4 characterized in that the working solution is H2O / NH3 or UNO3 / NH3.
    25
    类似技术:
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    同族专利:
    公开号 | 公开日
    ES2555704B1|2017-10-27|
    EP3150940A4|2018-02-07|
    US20170153046A1|2017-06-01|
    ES2555704R2|2017-01-16|
    US10845100B2|2020-11-24|
    WO2017001708A1|2017-01-05|
    EP3150940A1|2017-04-05|
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